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HRID 462820作成日:2026年10月26日

Chlorine → Pyridine, 2,3,4,5-tetrachloro-6-(trichloromethyl)-

https://huagongshe.com/reaction/462820

反応式

関与物質

役割名称HCID仕込み量
反応物ChlorineHCID 24526—
反応物Pyridine, 3,4,5-trichloro-2-(trichloromethyl)-HCID 70990—
生成物Pyridine, 2,3,4,5-tetrachloro-6-(trichloromethyl)-HCID 7081165%

反応手順

Summarizing Example 1, starting with fifty grams of a mixture rich in 3,4,5-trichloro-2-trichloromethyl pyridine, the analysis of which is set forth in Table One, and which contained 3% by weight ferric chloride, its chlorination with 70 grams per hour of chlorine, sparged into a 250 ml glass reactor at 200° C. for 5 hours, resulted in a product the analysis of which is set forth in Table One. As will be noted, a molar yield in excess of 65% of 3,4,5,6-tetrachloro-2-trichloromethyl pyridine based on 3,4,5-trichloro-2-trichloromethyl pyridine conversion was obtained.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US04517369
出典データセットuspto-grants-1985_05
ORD IDord-15312b5ae56c4930b6453021c4f264c6
出典メモuspto-grants-1985_05