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Chlorine → Pyridine, 2,3,4,5-tetrachloro-6-(trichloromethyl)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Chlorine | HCID 24526 | — |
| 反応物 | Pyridine, 3,4,5-trichloro-2-(trichloromethyl)- | HCID 70990 | — |
| 生成物 | Pyridine, 2,3,4,5-tetrachloro-6-(trichloromethyl)- | HCID 70811 | 65% |
反応手順
Summarizing Example 1, starting with fifty grams of a mixture rich in 3,4,5-trichloro-2-trichloromethyl pyridine, the analysis of which is set forth in Table One, and which contained 3% by weight ferric chloride, its chlorination with 70 grams per hour of chlorine, sparged into a 250 ml glass reactor at 200° C. for 5 hours, resulted in a product the analysis of which is set forth in Table One. As will be noted, a molar yield in excess of 65% of 3,4,5,6-tetrachloro-2-trichloromethyl pyridine based on 3,4,5-trichloro-2-trichloromethyl pyridine conversion was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04517369 |
| 出典データセット | uspto-grants-1985_05 |
| ORD ID | ord-15312b5ae56c4930b6453021c4f264c6 |
| 出典メモ | uspto-grants-1985_05 |