Hydrogen Peroxide → 8-[4-(4-Acetamido-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

反応式

[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[C:26]3[NH:25][C:24](=[O:27])[O:23][C:22]([CH3:29])([CH3:28])[C:21]=3[CH:20]=[CH:19][CH:18]=2)=[CH:7][CH:6]=1)(=[O:3])[CH3:2].[OH:30]O>>[C:1]([NH:4][C:5]1[CH:6]=[CH:7][C:8]([S:11]([CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[C:26]3[NH:25][C:24](=[O:27])[O:23][C:22]([CH3:29])([CH3:28])[C:21]=3[CH:20]=[CH:19][CH:18]=2)=[O:30])=[CH:9][CH:10]=1)(=[O:3])[CH3:2]

参加物

反応物 2

HCID 784Hydrogen Peroxide

HCID 202817098-[4-(4-Acetamido-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

生成物 1

HCID 202817898-[4-(4-Acetamido-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

実験手順

Prepared analogously to Example 2 from 8-[4-(4-acetamidophenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

出典と根拠

ORDレコード: ord-26e423c47d6846afb6041f9354303280
出典データセット: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04518597

反応ノート

読み込み中…