Hydrogen Peroxide → 8-[4-(3,4-Dimethoxy-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

反応式

[CH3:1][O:2][C:3]1[CH:4]=[C:5]([S:11][CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[C:26]3[NH:25][C:24](=[O:27])[O:23][C:22]([CH3:29])([CH3:28])[C:21]=3[CH:20]=[CH:19][CH:18]=2)[CH:6]=[CH:7][C:8]=1[O:9][CH3:10].[OH:30]O>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([S:11]([CH2:12][CH2:13][CH2:14][CH2:15][O:16][C:17]2[C:26]3[NH:25][C:24](=[O:27])[O:23][C:22]([CH3:29])([CH3:28])[C:21]=3[CH:20]=[CH:19][CH:18]=2)=[O:30])[CH:6]=[CH:7][C:8]=1[O:9][CH3:10]

参加物

反応物 2

HCID 784Hydrogen Peroxide

HCID 202816738-[4-(3,4-Dimethoxy-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

生成物 1

HCID 202818688-[4-(3,4-Dimethoxy-phenylsulfinyl)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

実験手順

Prepared analogously to Example 2 from 8-[4-(3,4-dimethoxy-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

出典と根拠

ORDレコード: ord-bfc73a45c8024fd18dc76d488adbe1b9
出典データセット: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04518597

反応ノート

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