Hydrogen Peroxide → 6-[4-(4-Chloro-phenylsulfinyl)-butoxy]-8-chloro-4,4-dimethyl-4H-3,1-benzoxazin-2-one

反応式

[Cl:1][C:2]1[C:11]2[NH:10][C:9](=[O:12])[O:8][C:7]([CH3:14])([CH3:13])[C:6]=2[CH:5]=[C:4]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][S:20][C:21]2[CH:26]=[CH:25][C:24]([Cl:27])=[CH:23][CH:22]=2)[CH:3]=1.[OH:28]O>>[Cl:27][C:24]1[CH:23]=[CH:22][C:21]([S:20]([CH2:19][CH2:18][CH2:17][CH2:16][O:15][C:4]2[CH:3]=[C:2]([Cl:1])[C:11]3[NH:10][C:9](=[O:12])[O:8][C:7]([CH3:14])([CH3:13])[C:6]=3[CH:5]=2)=[O:28])=[CH:26][CH:25]=1

参加物

反応物 2

HCID 784Hydrogen Peroxide

HCID 202818188-chloro-6-[4-(4-chloro-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

生成物 1

HCID 202818156-[4-(4-Chloro-phenylsulfinyl)-butoxy]-8-chloro-4,4-dimethyl-4H-3,1-benzoxazin-2-one

実験手順

Prepared analogously to Example 2 from 8-chloro-6-[4-(4-chloro-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

出典と根拠

ORDレコード: ord-1384e7428c3442c782c6597c1e16c956
出典データセット: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04518597

反応ノート

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