Hydrogen Peroxide → 6-[4-(4-Chloro-phenylsulfinyl)-butoxy]-7-chloro-4,4-dimethyl-4H-3,1-benzoxazin-2-one

反応式

[Cl:1][C:2]1[C:14]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][S:20][C:21]2[CH:26]=[CH:25][C:24]([Cl:27])=[CH:23][CH:22]=2)=[CH:13][C:5]2[C:6]([CH3:12])([CH3:11])[O:7][C:8](=[O:10])[NH:9][C:4]=2[CH:3]=1.[OH:28]O>>[Cl:27][C:24]1[CH:23]=[CH:22][C:21]([S:20]([CH2:19][CH2:18][CH2:17][CH2:16][O:15][C:14]2[C:2]([Cl:1])=[CH:3][C:4]3[NH:9][C:8](=[O:10])[O:7][C:6]([CH3:12])([CH3:11])[C:5]=3[CH:13]=2)=[O:28])=[CH:26][CH:25]=1

参加物

反応物 2

HCID 784Hydrogen Peroxide

HCID 202818027-chloro-6-[4-(4-chloro-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one

生成物 1

HCID 202817976-[4-(4-Chloro-phenylsulfinyl)-butoxy]-7-chloro-4,4-dimethyl-4H-3,1-benzoxazin-2-one

実験手順

Prepared analogously to Example 2 from 7-chloro-6-[4-(4-chloro-phenylmercapto)-butoxy]-4,4-dimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

出典と根拠

ORDレコード: ord-6ba9f557360d4d599e2181d885265562
出典データセット: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04518597

反応ノート

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