Hydrogen Peroxide → 6-(4-Phenylsulfinyl-butoxy)-4,4,8-trimethyl-4H-3,1-benzoxazin-2-one

反応式

[C:1]1([S:7][CH2:8][CH2:9][CH2:10][CH2:11][O:12][C:13]2[CH:14]=[C:15]([CH3:26])[C:16]3[NH:21][C:20](=[O:22])[O:19][C:18]([CH3:24])([CH3:23])[C:17]=3[CH:25]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH:27]O>>[C:1]1([S:7]([CH2:8][CH2:9][CH2:10][CH2:11][O:12][C:13]2[CH:14]=[C:15]([CH3:26])[C:16]3[NH:21][C:20](=[O:22])[O:19][C:18]([CH3:23])([CH3:24])[C:17]=3[CH:25]=2)=[O:27])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

反応物 2

HCID 784Hydrogen Peroxide

HCID 202818016-(4-Phenylmercapto-butoxy)-4,4,8-trimethyl-4H-3,1-benzoxazin-2-one

生成物 1

HCID 202817546-(4-Phenylsulfinyl-butoxy)-4,4,8-trimethyl-4H-3,1-benzoxazin-2-one

実験手順

Prepared analogously to Example 2 from 6-(4-phenylmercapto-butoxy)-4,4,8-trimethyl-4H-3,1-benzoxazin-2-one and hydrogen peroxide.

出典と根拠

ORDレコード: ord-32ac63b211b24cf09e7ddfaf5e9177fd
出典データセット: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04518597

反応ノート

読み込み中…