7-chloro-6-hydroxy-4,4-dimethyl-4H-3,1-benzoxazin-2-one → 7-Chloro-6-(4-phenylsulfinyl-butoxy)-4,4-dimethyl-4H-3,1-benzoxazin-2-one

反応式

[Cl:1][C:2]1[C:14]([OH:15])=[CH:13][C:5]2[C:6]([CH3:12])([CH3:11])[O:7][C:8](=[O:10])[NH:9][C:4]=2[CH:3]=1.[C:16]1([S:22]([CH2:24][CH2:25][CH2:26][CH2:27]Br)=[O:23])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1>>[Cl:1][C:2]1[C:14]([O:15][CH2:27][CH2:26][CH2:25][CH2:24][S:22]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)=[O:23])=[CH:13][C:5]2[C:6]([CH3:12])([CH3:11])[O:7][C:8](=[O:10])[NH:9][C:4]=2[CH:3]=1

参加物

反応物 2

HCID 202818057-chloro-6-hydroxy-4,4-dimethyl-4H-3,1-benzoxazin-2-one

HCID 545301224-Phenylsulfinylbutylbromide

生成物 1

HCID 202818827-Chloro-6-(4-phenylsulfinyl-butoxy)-4,4-dimethyl-4H-3,1-benzoxazin-2-one

実験手順

Prepared analogously to Example 4 from 7-chloro-6-hydroxy-4,4-dimethyl-4H-3,1-benzoxazin-2-one and 4-phenylsulfinyl-butylbromide.

出典と根拠

ORDレコード: ord-93cb906e5cae44e383a7b5bf82067a7d
出典データセット: uspto-grants-1985_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04518597

反応ノート

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