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Chlorotrimethylsilane → (Hexyloxy)trimethylsilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Chlorotrimethylsilane | HCID 6397 | — |
| 反応物 | 1-Hexanol | HCID 8103 | — |
| 反応物 | N,N'-Bis(trimethylsilyl)ethylenediamine | HCID 74569 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | (Hexyloxy)trimethylsilane | HCID 519489 | 59% |
反応手順
To hexan-1-ol (5.1 g, 0.05 mole) in dichloromethane (50 ml) were added trimethylchlorosilane (1.81 g, 0.0166 mole) and N,N'-bis(trimethylsilyl)ethlenediamine (3.44 g, 0.0166 mole). The mixture was stirred under reflux for 30 minutes, filtered and the solvent removed. The residue, hexanoxytrimethylsilane, was obtained in 59% yield (5.15 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04518787 |
| 出典データセット | uspto-grants-1985_05 |
| ORD ID | ord-492d73126dca42c6956bc86f6ab2124b |
| 出典メモ | uspto-grants-1985_05 |