関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 反応物 | Monomethyl azelate | HCID 75009 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | Methyl 9-chloro-9-oxononanoate | HCID 544297 | — |
反応手順
In a separate process, 23.9 g of azelaic monomethylester was dissolved in 30 ml chloroform. Oxalylchloride (15 ml) was added, all at once, and the mixture refluxed 2 hours at 50° C. The mixture was cooled; excess solvent and oxalylchloride were evaporated. After distillation, 25.8 g of CH3OCO(CH2)7COCl was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04544668 |
|---|
| 出典データセット | uspto-grants-1985_10 |
|---|
| ORD ID | ord-e70b7d36c96148e3b9e913f07b19395b |
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| 出典メモ | uspto-grants-1985_10 |
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