化工社化工社 化学情報印刷レポート · 研究参考用
2,5-Dianilinoterephthalic acid → 3-Acridinecarboxylic acid, 9,10-dihydro-9-oxo-2-(phenylamino)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2,5-Dianilinoterephthalic acid | HCID 82351 | — |
| 溶媒 | Phosphoric Acid | HCID 1004 | — |
| 生成物 | 3-Acridinecarboxylic acid, 9,10-dihydro-9-oxo-2-(phenylamino)- | HCID 11067475 | — |
反応手順
A process is disclosed wherein 2,5-di(phenylamino) terephthalic acid is half-cyclized by dissolving it in a mixture of polyphosphoric acid and phosphoric acid and heating at 100°-120° C. to form 2-(phenyl)amino-3-carboxy-9(10H)acridone (ACA). The ACA is decarboxylated to form 2-(phenyl)amino-9(10H)acridone, also known as 2-anilinoacridone, by dissolving it in tetramethylene sulfone and heating in the presence of a basic cupric carbonate catalyst.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04544746 |
| 出典データセット | uspto-grants-1985_10 |
| ORD ID | ord-841256f29c574e16a8539eaeb3b9e9bd |
| 出典メモ | uspto-grants-1985_10 |