関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 2-Amino-2-methylbutyronitrile | HCID 15576830 | — |
| 触媒 | Hexadecyltrimethylammonium chloride | HCID 8154 | — |
| 生成物 | 2,2'-Azobis(2-methylbutyronitrile) | HCID 93079 | 173.8% |
反応手順
The resulting aqueous dispersion of N,N-dichloro-2-amino-2-methylbutanenitrile was adjusted to pH7 by the addition of caustic soda and 3 ml of "Arquad 16-29%" surfactant added. After addition of a further 2.2 equivalents of caustic soda, 16.8 gm of 2-amino-2-methylbutanenitrile were added slowly over 60 minutes whilst maintaining the temperature at 20° C. The resulting suspension was filtered, washed and dried to yield 28.6 gm of the title compound (yield 84.2%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US04546174 |
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| 出典データセット | uspto-grants-1985_10 |
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| ORD ID | ord-53d103c42b304bc9a113775e85116898 |
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| 出典メモ | uspto-grants-1985_10 |
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