化工社化工社 化学情報印刷レポート · 研究参考用
Boron trifluoride → Bis(1-methylethyl)benzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Boron trifluoride | HCID 6356 | — |
| 反応物 | Cumene | HCID 7406 | — |
| 反応物 | Triisopropylbenzene | HCID 13880201 | — |
| 溶媒 | Hydrofluoric Acid | HCID 14917 | — |
| 生成物 | Bis(1-methylethyl)benzene | HCID 11345 | 36% |
反応手順
12 g (0.1 mol) cumene and 10 g (0.05 mol) triisopropylbenzene are dissolved in 150 ml of anhydrous hydrogen fluoride at a temperature between -20° and 0°. While stirring the reaction mixture at this temperature, it is saturated with boron trifluoride and stirring is continued for two hours. After workup, as in Example 5, 36% diisopropylbenzene was obtained, comprised of 99.2% of the meta and 0.8% of the para isomer.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04547604 |
| 出典データセット | uspto-grants-1985_10 |
| ORD ID | ord-5e9779d0610a4664b682dbf6de652117 |
| 出典メモ | uspto-grants-1985_10 |