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HRID 464494作成日:2026年10月25日

Boron trifluoride → Bis(1-methylethyl)benzene

https://huagongshe.com/reaction/464494

反応式

関与物質

役割名称HCID仕込み量
反応物Boron trifluorideHCID 6356—
反応物CumeneHCID 7406—
反応物TriisopropylbenzeneHCID 13880201—
溶媒Hydrofluoric AcidHCID 14917—
生成物Bis(1-methylethyl)benzeneHCID 1134536%

反応手順

12 g (0.1 mol) cumene and 10 g (0.05 mol) triisopropylbenzene are dissolved in 150 ml of anhydrous hydrogen fluoride at a temperature between -20° and 0°. While stirring the reaction mixture at this temperature, it is saturated with boron trifluoride and stirring is continued for two hours. After workup, as in Example 5, 36% diisopropylbenzene was obtained, comprised of 99.2% of the meta and 0.8% of the para isomer.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US04547604
出典データセットuspto-grants-1985_10
ORD IDord-5e9779d0610a4664b682dbf6de652117
出典メモuspto-grants-1985_10