化工社化工社 化学情報印刷レポート · 研究参考用
1-Bromooctadecane → 3,5-Dioctadecyloxybenzoic acid ethyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Bromooctadecane | HCID 8218 | — |
| 反応物 | Benzoic acid, 3,5-dihydroxy-, ethyl ester | HCID 20098 | — |
| 反応物 | Sodium | HCID 5360545 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 3,5-Dioctadecyloxybenzoic acid ethyl ester | HCID 53731475 | — |
反応手順
50 m mol of 3,5-dihydroxybenzoic acid ethyl ester, 120 m mol of stearyl bromide, and 110 m mol of sodium were made to react in ethanol, thereby forming 35 m mol of 3,5-dioctadecyloxybenzoic acid ethyl ester. This ester, 25 m mol, was first hydrolyzed into the corresponding acid, which in turn was converted into its acid chloride. The acid chloride was reacted in the same way as in Example 1, whereby 10 m mol of N-(3,5-dioctadecyloxybenzoyl)-N'methylsulfonyl-p-quinonediimine was obtained which is represented by the following formula: ##STR30##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05153680 |
| 出典データセット | uspto-grants-1992_10 |
| ORD ID | ord-0708f62d736c4ba789917a02358715dc |
| 出典メモ | uspto-grants-1992_10 |