1-Bromo-4-(trimethoxymethyl)benzene → HCID 18953340、化合物
反応式
[CH3:1][O:2][C:3]([O:13][CH3:14])([O:11][CH3:12])[C:4]1[CH:9]=[CH:8][C:7](Br)=[CH:6][CH:5]=1.C[C:16](C)(C)[CH2:17][C:18]([CH2:23]O)([CH2:21]O)[CH2:19]O>Cl>[CH3:23][C:18]([CH3:19])([CH3:21])[CH2:17][C:16]12[CH2:14][O:13][C:3]([C:4]3[CH:9]=[CH:8][C:7]([CH2:5][CH2:4][CH2:3][O:2][CH3:1])=[CH:6][CH:5]=3)([O:11][CH2:12]1)[O:2][CH2:1]2参加物
4
実験手順
Trimethyl 4-bromo-orthobenzoate (1.5 g.) (McElvain and Venerable, J. Amer.Chem.Soc., 1950,72,1661) was added to 2-(2,2-dimethylpropyl)-2-hydroxymethyl-propan-1,3-diol (1.0 g.). One drop of concentrated hydrochloric acid was added and the mixture was maintained at 140° for one hour, under a current of nitrogen. The volatile components were removed in vacuo (1.0 mm), at 140° C.