関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | tert-Butyl hydroperoxide | HCID 6410 | — |
| 反応物 | 1-Octene | HCID 8125 | — |
| 反応物 | Potassium Acetate | HCID 517044 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | alpha-Hexyl-gamma-butyrolactone | HCID 86736 | 65% |
反応手順
A stock solution was prepared by heating at 115° C. 500 milliliters of acetic acid, 150 grams of potassium acetate, and 245 grams of manganous acetate tetrahydrate, Mn(OCOCH3)2.4H2O. A 50-milliliter aliquot of the stock solution was added to 2 milliliters of a 0.312 molar solution of tertiary butyl hydroperoxide in acetic acid. The solution also contained 400 microliters of octene-1. After heating, a hexyl gamma-butyrolactone was obtained with a 65% yield based on the tertiary butyl hydroperoxide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04175089 |
|---|
| 出典データセット | uspto-grants-1979_11 |
|---|
| ORD ID | ord-2a15ae7a07b443928874c15f383242ed |
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| 出典メモ | uspto-grants-1979_11 |
|---|
