Resorcinol → 1,3-Bis(2-hydroxy-3-phenoxypropyloxy)benzene
反応式
[C:1]1([CH:8]=[CH:7][CH:6]=[C:4]([OH:5])[CH:3]=1)[OH:2].[CH2:9]([O:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[CH:10]1[O:12][CH2:11]1.[C:20]1(C2NC=CN=2)[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>>[OH:12][CH:10]([CH2:9][O:13][C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[CH2:11][O:2][C:1]1[CH:8]=[CH:7][CH:6]=[C:4]([O:5][CH2:11][CH:10]([OH:12])[CH2:9][O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:3]=1参加物
4
実験手順
Resorcinol (110 g), phenyl glycidyl ether (329.5 g) and 2-phenylimidazole (0.4 ) were stirred and heated at 130° for 2 hours, then at 150° for 31/2 hours. The product had a negligible epoxy content (only 0.2 equiv./kg).
後処理
- temperatureheated at 130° for 2 hours
- customat 150°
- custom2 hours