関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3-Thiocresol | HCID 7930 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | decyl N-trifluoroacetyl-N-(dichlorophosphonomethyl)glycinate | HCID 53672523 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | n-decyl N-trifluoroacetyl-N-(bis(m-methylphenylthio)phosphonomethyl)glycinate | HCID 53947343 | — |
反応手順
To a solution of n-decyl N-trifluoroacetyl-N-(dichlorophosphonomethyl)glycinate (4.42 g, 0.01 mole) in 200 ml. of ether was added a solution of m-methylthiophenol (2.48 g, 0.02 mole) and triethylamine (2.02 g, 0.02 mole) in 50 ml. of ether. The resulting mixture was stirred for 16 hours at 20° C., then filtered. The filtrate was concentrated in vacuo to yield an oil which was chromatographed on silica gel (eluted with methylene chloride) to yield n-decyl N-trifluoroacetyl-N-(bis(m-methylphenylthio)phosphonomethyl)glycinate as an oil, nD27 =1.5267.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US04175946 |
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| 出典データセット | uspto-grants-1979_11 |
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| ORD ID | ord-a03f3ac4e3d3480db19e1447db288fff |
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| 出典メモ | uspto-grants-1979_11 |
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