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p-Toluidine → N-(p-phenylbenzylidene)-p-methylaniline
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | p-Toluidine | HCID 7813 | — |
| 反応物 | (1,1'-Biphenyl)-4-carboxaldehyde | HCID 76689 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | N-(p-phenylbenzylidene)-p-methylaniline | HCID 13017554 | — |
反応手順
p-Toluidine (0.20 mole), 4-biphenylcarboxaldehyde (0.20 mole), and IRC-50 (weakly acidic) ion exchange resin (0.5 g.) were azeotropically refluxed in toluene (150 cc). The required amount of water had been removed after 3 hours. The solvent was removed on the rotary evaporator and the residue was recrystallized with 95% ethanol to yield N-(p-phenylbenzylidene)-p-methylaniline; m.p. 137°-139° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04176198 |
| 出典データセット | uspto-grants-1979_11 |
| ORD ID | ord-6885f8cc803248b0b118c62099c312e2 |
| 出典メモ | uspto-grants-1979_11 |