関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Thiophenol | HCID 7969 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | Dinitrobenzonitrile | HCID 520718 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | 2-Nitro-6-(phenylthio)benzonitrile | HCID 15198241 | — |
反応手順
To a mixture of 2,6-dinitrobenzonitrile (2.0 g, 10.36 mmol) and K2CO3 (1.43 g, 10.36 mmol) in 5 mL of anhydrous DMF was added PhSH (1.14 ml in 5 mL of DMF) dropwise under nitrogen at 0° C. After the completion of addition, the reaction mixture was stirred at 0° C. for 0.5 hr. Then the reaction mixture was poured into 50 mL of water, the resultant precipitation was collected by filtration, washed with water and dried in the air to give the title product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08633186B2 |
|---|
| 出典データセット | uspto-grants-2014_01 |
|---|
| ORD ID | ord-a274fdeb20124f60921de4318030df38 |
|---|
| 出典メモ | uspto-grants-2014_01 |
|---|
