化工社化工社 化学情報印刷レポート · 研究参考用
Dinitrobenzonitrile → Tert-butyl 4-(2-cyano-3-nitrophenoxy)butylcarbamate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dinitrobenzonitrile | HCID 520718 | — |
| 反応物 | tert-Butyl N-(4-hydroxybutyl)carbamate | HCID 545141 | — |
| 生成物 | Tert-butyl 4-(2-cyano-3-nitrophenoxy)butylcarbamate | HCID 66665900 | 7% |
反応手順
Prepared as in Example 215c from tert-butyl 4-hydroxybutylcarbamate and 2,6-dinitrobenzonitrile in 7% yield as a pale yellow solid. 1H NMR (400 MHz, DMSO-d6) δ 1.35 (s, 9H), 1.52-1.55 (m, 2H), 1.72-1.76 (m, 2H), 2.94-2.99 (m, 2H), 4.24 (t, J=6.8 Hz, 2H), 6.86 (brs, 1H), 7.69-7.72 (m, 1H), 7.85-7.90 (m, 2H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08633186B2 |
| 出典データセット | uspto-grants-2014_01 |
| ORD ID | ord-869e344172e04172aae62636868ef67d |
| 出典メモ | uspto-grants-2014_01 |