Carbon Dioxide → Benzeneacetic acid, 4-bromo-

反応式

[Br:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8](C(O)=O)[C:9]([OH:11])=[O:10])=[CH:4][CH:3]=1.C(=O)=O>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:8][C:9]([OH:11])=[O:10])=[CH:6][CH:7]=1

参加物

反応物 2

HCID 280Carbon Dioxide

HCID 21866616Propanedioic acid, 2-(4-bromophenyl)-

生成物 1

HCID 74654Benzeneacetic acid, 4-bromo-収率 1,099.1%

実験手順

2-(4-Bromophenyl)malonic acid (36 g, 11 mmol) was heated at 165° C. until evolution of CO2. the production was crystallized from petrol ether to give 2-(4-bromophenyl)acetic acid (26 g, 87%).

後処理

customthe production was crystallized from petrol ether

出典と根拠

ORDレコード: ord-0c71970627204bb385732ec691183e7b
出典データセット: uspto-grants-2014_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08633212B2

反応ノート

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