関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | 5,7-Dinitro-2,3-dihydrobenzofuran | HCID 19836322 | — |
| 溶媒 | Formamide | HCID 713 | — |
| 生成物 | 2-(2-Amino-3,5-dinitrophenyl)ethanol | HCID 19836340 | — |
反応手順
0.17 Mole (35.7 g) of 2,3-dihydro-5,7-dinitrobenzofuran, prepared according to Chatelus Ann. Chim. [12], 4,505-547 (1949), is suspended in 350 ml of 20% strength ammonia solution and 220 ml of formamide. After 8 hours' heating at 110° C., a further 100 ml of 20% strength ammonia solution are added. Heating is maintained for 4 hours. When the reaction medium is cooled, the expected product precipitates.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04727192 |
|---|
| 出典データセット | uspto-grants-1988_02 |
|---|
| ORD ID | ord-a92e3cb04a4c44e3b5b26d5940e91aac |
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| 出典メモ | uspto-grants-1988_02 |
|---|
