化工社化工社 化学情報印刷レポート · 研究参考用
Pyrazine → Decylbenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyrazine | HCID 9261 | — |
| 反応物 | 1-Iododecane | HCID 16314 | — |
| 反応物 | HCID 178418255 | HCID 178418255 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | Decylbenzene | HCID 7716 | 71% |
反応手順
1-Iododecane (134.1 mg, 0.5 mmol) and a THF solution (0.77 mL, 0.97 M, 0.75 mmol) of phenylmagnesium bromide were used as starting materials, and reacted as in Entry 1. Conditions: The THF solution of phenylmagnesium bromide was added dropwise at 40° C. over 2 hours. 1H-NMR analysis was conducted using pyrazine (29.0 mg, 0.36 mmol) as an internal standard (yield 71%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08637710B2 |
| 出典データセット | uspto-grants-2014_01 |
| ORD ID | ord-444823a2407942948fa5a1876215c2b5 |
| 出典メモ | uspto-grants-2014_01 |