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Ethyl bromoacetate → Ethyl [(4-Chlorophenyl)thio]acetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl bromoacetate | HCID 7748 | — |
| 反応物 | p-Chlorothiophenol | HCID 7815 | — |
| 反応物 | Acetic acid, (phenylthio)-, ethyl ester | HCID 97312 | — |
| 溶媒 | Sodium ethoxide | HCID 2723922 | — |
| 生成物 | Ethyl [(4-Chlorophenyl)thio]acetate | HCID 257604 | — |
反応手順
The procedure is as in Example 2 for the preparation of ethyl (phenylthio)acetate starting with ethyl bromoacetate (16.7 g), a 2M ethanolic solution of sodium ethylate (50 cc) and 4-chlorothiophenol (14.5 g). Ethyl (4-chlorophenylthio)acetate (20.7 g) is thereby obtained, and is used in the crude state in the subsequent phases.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04886835 |
| 出典データセット | uspto-grants-1989_12 |
| ORD ID | ord-bfcc6857512a4d6088569b137be7b768 |
| 出典メモ | uspto-grants-1989_12 |