Phenol → Hydroxyphenylstearic acid

HRID 477416

反応式

HRID 477416 の反応式
[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[C:21]1(O)[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1.P(=O)(O)(O)[OH:29]>>[OH:29][C:2]([C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[C:1]([OH:20])=[O:19]

参加物

4

反応物 3

HCID 996PhenolHCID 1004Phosphoric AcidHCID 445639Oleic Acid

生成物 1

HCID 67710449Hydroxyphenylstearic acid

反応条件

温度
200 °C

実験手順

A 500-ml autoclave was charged with 166 g of commercial oleic acid (product of Nippon Oils & Fats Co., Ltd.), 169 g of phenol (product of Katayama Kagaku Kogyo K.K.), 6.6 g of activated clay (Nippon Kassei Hakudo K.K.), and 0.13 g of 85% aqueous phosphoric acid (product of Katayama Kagaku Kogyo K.K.). After purging the autoclave with nitrogen gas, the contents were allowed to react by heating at 200° C. for 4 hours. After completion of the reaction, the activated clay was filtered off and the unreacted phenol was distilled away at 80°-100° C., 3 mmHg to yield a yellow viscous reaction product in an amount of 224 g.

後処理

  1. customAfter purging the autoclave with nitrogen gas
  2. customto react
  3. customAfter completion of the reaction
  4. filtrationthe activated clay was filtered off
  5. distillationthe unreacted phenol was distilled away at 80°-100° C.
  6. custom3 mmHg to yield a yellow viscous reaction product in an amount of 224 g

出典と根拠

ORDレコード
ord-c1c552b8069745d8a6d1ddec01b86e24
出典データセット
uspto-grants-1989_12
特許番号
US04888132

関連ノート

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