化工社化工社 化学情報印刷レポート · 研究参考用
Cyclohexanone, 2-hydroxy- → 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Cyclohexanone, 2-hydroxy- | HCID 10785 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | 1-Penten-3-one | HCID 15394 | — |
| 反応物 | Lithium diisopropylamide | HCID 2724682 | — |
| 反応物 | 2,3-Dimethyl-2-cyclohexen-1-one | HCID 10887898 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone | HCID 10909881 | — |
反応手順
This material is prepared according to the procedure for Preparation 5 wherein 2-hydroxycyclohexanone is substituted for 2,3-dimethylcyclohexenone, methylbutenone is substituted for MVK, and 2N KOH in MeOH is substituted fro LDA in THF.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04889947 |
| 出典データセット | uspto-grants-1989_12 |
| ORD ID | ord-ace3d167981649f5b92a1c86044c0fb5 |
| 出典メモ | uspto-grants-1989_12 |