化工社化工社 化学情報印刷レポート · 研究参考用
Carvone, (+-)- → 4a-Carboethoxy-7-hydroxy-4,4a,5,6-tetrahydro-2(3H)-naphthalenone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Carvone, (+-)- | HCID 7439 | — |
| 反応物 | 1-Penten-3-one | HCID 15394 | — |
| 反応物 | Ethyl 3-chloropropionate | HCID 69341 | — |
| 反応物 | 4-Carbethoxy-3-methyl-2-cyclohexen-1-one | HCID 79020 | — |
| 生成物 | 4a-Carboethoxy-7-hydroxy-4,4a,5,6-tetrahydro-2(3H)-naphthalenone | HCID 13950339 | — |
反応手順
This material is prepared according to the procedure for Preparation 6 wherein Hagemann's ester (ethyl 2-methyl-4-oxocyclohex-2-enyl-1-carboxylate) is substituted for carvone and ethyl 3-chloropropionate is substituted for ethyl vinyl ketone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04889947 |
| 出典データセット | uspto-grants-1989_12 |
| ORD ID | ord-3f6f4f62c9f14855a8983544f3155d68 |
| 出典メモ | uspto-grants-1989_12 |