関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dimethylformamide | HCID 6228 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | N-Butylaniline | HCID 14310 | — |
| 反応物 | 2-Bromoheptane | HCID 16090 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N-Butyl-N-(heptan-2-YL)aniline | HCID 18000381 | 60% |
反応手順
A mixture of N-butylaniline (7.45 parts) anhydrous potassium carbonate (7.5 parts), 2-bromoheptane (13.5 parts) and DMF (25 parts) was stirred at 130° C. for 86 hours. The reaction mixture was poured into water, saturated with salt and extracted with ethyl acetate. The organic phase was washed with water, dried (MgSO4) and evaporated to leave N-butyl-N-(1-methylhexyl)aniline (11.8 parts, approximately 60% strength). This material had acetic anhydride (10 parts) added to it prior to further use.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06641620B1 |
|---|
| 出典データセット | uspto-grants-2003_11 |
|---|
| ORD ID | ord-b5b9ca4822df44e1bacd2841c36c81b6 |
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| 出典メモ | uspto-grants-2003_11 |
|---|
