化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Hydroxide → Sodium Nitrate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Nitrogen oxide (N2O4) | HCID 25352 | — |
| 反応物 | Nitrogen Dioxide | HCID 178526396 | — |
| 生成物 | Sodium Nitrate | HCID 24268 | — |
| 生成物 | Nitric Oxide | HCID 145068 | — |
| 生成物 | Sodium Nitrite | HCID 23668193 | — |
反応手順
Currently, the KSC oxidizer scrubbers react nitrogen tetroxide and/or nitrogen dioxide with nominally 25-weight-percent sodium hydroxide, which produces sodium nitrate, sodium nitrite, and nitric oxide. Nitrogen dioxide is in equilibrium with nitrogen tetroxide in the gas phase, reaction 1-61. Nitric oxide is not a primary gas-phase reactant, but it is produced during the liquid-phase reactions 1-65 and 1-66. Once produced, nitric oxide can either combine with nitrogen dioxide, reaction 1-62, or be oxidized by oxygen in the scrubber to nitrogen dioxide, reaction 1-63, to be reabsorbed in the scrubber liquor, reactions 1-64 to 1-67. However, the nitric oxide can escape reaction with the scrubber liquor be released into the atmosphere.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06641638B1 |
| 出典データセット | uspto-grants-2003_11 |
| ORD ID | ord-33a990b204604064954703ef2ae47fbf |
| 出典メモ | uspto-grants-2003_11 |