化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Iodide → 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-[4-(3,7-dimethyloctyloxy)phenyl]-fluorene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Iodide | HCID 5238 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | 1-Chloro-3,7-dimethyloctane | HCID 227360 | — |
| 反応物 | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene | HCID 18766847 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 溶媒 | Ethyl Acetate | HCID 8857 | — |
| 生成物 | 2,7-Dibromo-9-(2,5-dimethylphenyl)-9-[4-(3,7-dimethyloctyloxy)phenyl]-fluorene | HCID 18766842 | — |
反応手順
52 g of 2,7-dibromo-9-(2,5-dimethylphenyl)-9-(4-hydroxyphenyl)fluorene were refluxed with 18 g of 3,7-dimethyloctyl chloride, 80 ml of ethanol, 7 g of KOH and 1 g of NaI for 5 days. According to TLC, the reaction was complete after this time. The solvent was stripped off, ethyl acetate was added, and the precipitate was filtered off with suction and rinsed a number of times with ethyl acetate. The organic phase was dried, and the solvent was stripped off.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06653438B1 |
| 出典データセット | uspto-grants-2003_11 |
| ORD ID | ord-6d04b460c8404279aa774d3bf11f9768 |
| 出典メモ | uspto-grants-2003_11 |