Tetrafluoroboric acid → Diphenyliodonium Tetrafluoroborate

HRID 481145ノート

反応式

HRID 481145 の反応式
[F:1][B-:2]([F:5])([F:4])[F:3].[H+].P(O)(O)O.[Cl-].[C:12]1([I+:18][C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>O.F[B-](F)(F)F.[Ag+]>[F:1][B-:2]([F:5])([F:4])[F:3].[C:19]1([I+:18][C:12]2[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=1

参加物

6

反応物 3

HCID 28118Tetrafluoroboric acidHCID 73870Diphenyliodonium chlorideHCID 107909Phosphorous acid

生成物 1

HCID 11122160Diphenyliodonium Tetrafluoroborate

試薬・触媒・溶媒 2

HCID 159722Silver tetrafluoroborate触媒HCID 962Water溶媒

実験手順

The aromatic iodonium complex salts may be prepared by metathesis of corresponding aromatic iodonium simple salts (such as, for example, diphenyliodonium bisulfate) in accordance with the teachings of Beringer et al., J. Am. Chem. Soc., 81,342 (1959). Thus, for example, the complex salt diphenyliodonium tetrafluoroborate is prepared by the addition at 60° C. of an aqueous solution containing 29.2 g silver fluoroborate, 2 g fluoroboric acid, and 0.5 g phosphorous acid in about 30 ml of water to a solution of 44 g (139 millimoles) of diphenyliodonium chloride. The silver halide that precipitates is filtered off and the filtrate concentrated to yield diphenyliodonium fluoroborate which may be purified by recrystallization.

後処理

  1. customis prepared by the addition at 60° C. of an aqueous solution
  2. customThe silver halide that precipitates
  3. filtrationis filtered off
  4. concentrationthe filtrate concentrated

出典と根拠

ORDレコード
ord-675f36f9fc354784b4b54dca52c9e683
出典データセット
uspto-grants-2003_11
特許番号
US06653486B2

反応ノート

読み込み中…