化工社化工社 化学情報印刷レポート · 研究参考用
Oxalyl chloride → Benzoyl chloride, 4-(tetradecyloxy)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxalyl chloride | HCID 65578 | — |
| 反応物 | 4-(Tetradecyloxy)benzoic acid | HCID 289410 | — |
| 触媒 | Chloroform | HCID 6212 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Benzoyl chloride, 4-(tetradecyloxy)- | HCID 9998158 | 102.4% |
反応手順
A mixture of 50 g of p-(tetradecyloxy)benzoic acid and 28.46 g of oxalyl chloride in 500 ml of chloroform containing 10 drops of N,N-dimethylformamide is stirred for 18 hours at ambient temperature. The solvent is evaporated and the residue dissolved in ether, filtered and evaporated to give 54 g of the desired product as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05225425 |
| 出典データセット | uspto-grants-1993_07 |
| ORD ID | ord-1525193c99d5448682c4d78a085ff665 |
| 出典メモ | uspto-grants-1993_07 |