Allyl chloride → Trichloro(3-chloropropyl)silane
反応式
[CH2:1]([Cl:4])[CH:2]=[CH2:3].[Cl:5][SiH:6]([Cl:8])[Cl:7]>CCCCCC>[Cl:4][CH2:1][CH2:2][CH2:3][Si:6]([Cl:8])([Cl:7])[Cl:5].[CH2:1]([Si:6]([Cl:8])([Cl:7])[Cl:5])[CH2:2][CH3:3]参加物
5
反応条件
- 温度
- 23 °C
実験手順
A mixture of 15.306 grams of allyl chloride, 27.09 gram of trichlorosilane and 0.04 grams of [SG]--S--Pt sufficient to provide 1×10-5 mm Pt/SiH was stirred at 23° C. under a nitrogen atmosphere. The mixture was heated to 60° C. for 16 hours. The mixture was allowed to cool to ambient temperatures and was diluted with 50 ml of hexane and filtered. The filtrate was concentrated on a rotary evaporator to give 33 grams of a clear, colorless oil. Based on method of preparation, NMR and VPC analysis there was obtained about a 92% yield of γ-chloropropyltrichlorosilane and about an 8% yield of n-propyltrichlorosilane.
後処理
- customto provide 1×10-5 mm Pt/SiH
- temperatureThe mixture was heated to 60° C. for 16 hours
- temperatureto cool to ambient temperatures
- filtrationfiltered
- concentrationThe filtrate was concentrated on a rotary evaporator
- customto give 33 grams of a clear, colorless oil
- customBased on method of preparation, NMR
出典と根拠
- ORDレコード
- ord-2848430849c5408596f1f90b15d589d6
- 出典データセット
- uspto-grants-1985_08
- 特許番号
- US04533744
反応ノート
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