Acetic Acid → HCID 13335396、化合物
反応式
O[C:2]1([CH3:13])[CH:6]=[CH:5][C:4](=[O:7])[CH:3]1[CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:14]([OH:17])(=[O:16])[CH3:15]>>[CH2:8]([C:3]1[C:4](=[O:7])[CH2:5][CH:6]([O:17][C:14](=[O:16])[CH3:15])[C:2]=1[CH3:13])[CH2:9][CH2:10][CH2:11][CH3:12]参加物
3
実験手順
In the same apparatus as in Example 1, 3-hydroxy-2-n-pentyl-3-methyl-4-cyclopentenone (18.2 g) and acetic acid (55 ml) were charged and heated under reflux for 15 hours with agitation. After the completion of the reaction, acetic acid was evaporated off under reduced pressure. The residue was extracted with toluene (80 ml) and water (50 ml) and treated as in Example 1 to obtain 2-n-pentyl-3-methyl-4-acetoxy-2-cyclopentenone (20.6 g). Yield, 92%. B.P., 125°-135° C./0.2-0.5 mmHg.
後処理
- temperatureheated
- temperatureunder reflux for 15 hours with agitation
- customwas evaporated off under reduced pressure
- extractionThe residue was extracted with toluene (80 ml) and water (50 ml)
- additiontreated as in Example 1
出典と根拠
- ORDレコード
- ord-b325d5c9d338437b99c94e3fe3a683b5
- 出典データセット
- uspto-grants-1985_08
- 特許番号
- US04535182
反応ノート
読み込み中…