反応式
[C:1]([O:11][C:12]([C:15](I)([F:17])[F:16])([F:14])[F:13])([C:7]([F:10])([F:9])[F:8])([C:3]([F:6])([F:5])[F:4])[F:2]>C(O)(C)C.Cl[Hg]Cl>[C:1]([O:11][C:12]([CH:15]([F:17])[F:16])([F:13])[F:14])([C:7]([F:8])([F:10])[F:9])([C:3]([F:6])([F:5])[F:4])[F:2]参加物
4
反応条件
- 温度
- 55 °C
実験手順
A solution of (CF3)2CFOCF2CF2I (21.3 g) in isopropanol (8 mL) was added dropwise to a suspension of Al chips (1 g) and HgCl2 (0.4 g) in isopropanol (30 mL). After the exothermic reaction was completed, the reaction mixture was stirred for 1 hour at 55° C. The reaction mixture was then distilled and a fraction with a b.p. of less then 80° C. was collected. This fraction was washed with an aqueous HCl solution and then distilled over conc. H2SO4 to give (CF3)2CFOCF2CHF2 (11.8 g, 80% yield), b.p. 44 to 46° C. The 1H and 19F NMR were in accord with the assigned structure:
後処理
- customAfter the exothermic reaction
- distillationThe reaction mixture was then distilled
- customof less then 80° C. was collected
- washThis fraction was washed with an aqueous HCl solution
- distillationdistilled over conc. H2SO4
出典と根拠
- ORDレコード
- ord-83f8d50e146b4a3ebdf0a609467648ec
- 出典データセット
- uspto-grants-2004_03
- 特許番号
- US06703533B1
関連ノート
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