Trifluoroacetate → Bis(4-isopropylphenyl)iodosyl trifluoroacetate

HRID 485628ノート

反応式

HRID 485628 の反応式
[CH:1]([C:4]1[CH:9]=[CH:8][C:7]([I:10](=[O:12])=[O:11])=[CH:6][CH:5]=1)([CH3:3])[CH3:2].[F:13][C:14]([F:19])([F:18])[C:15]([O-])=[O:16].F[P-](F)(F)(F)(F)F.[K+]>O>[F:13][C:14]([F:19])([F:18])[C:15]([O:11][I:10]([C:7]1[CH:8]=[CH:9][C:4]([CH:1]([CH3:3])[CH3:2])=[CH:5][CH:6]=1)([C:7]1[CH:8]=[CH:9][C:4]([CH:1]([CH3:3])[CH3:2])=[CH:5][CH:6]=1)=[O:12])=[O:16]

参加物

5

反応物 3

HCID 84468TrifluoroacetateHCID 23688904Potassium hexafluorophosphateHCID 867402694-Isopropyliodoxybenzene

生成物 1

HCID 20268910Bis(4-isopropylphenyl)iodosyl trifluoroacetate

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

Bis(4-isopropylphenyl)iodosyl trifluoroacetate is prepared by a similar method to that described by F. M. Beringer and P. Boedlander, loc. cit.) using 4-isopropyliodoxybenzene (8.3 g) as starting material. The trifluoroacetate is dissolved in boiling water. Potassium hexafluorophosphate (2 molar excess) in water is added and the solution is allowed to cool. The crystals which form are collected by filtration and dried in air to afford bis(4-isopropylphenyl)iodosyl hexafluorophosphate (0.4 g) m.pt. 84° C. Spectroscopic analysis shows:

後処理

  1. temperatureto cool
  2. filtrationThe crystals which form are collected by filtration
  3. customdried in air

出典と根拠

ORDレコード
ord-7afbdc6c5a68453297dfdf3b7c237c50
出典データセット
uspto-grants-1985_08
特許番号
US04537725

反応ノート

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