Methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoate → [2-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonic acid

HRID 488153

反応式

HRID 488153 の反応式
O=C(CCC=C(C)CCC=C(C)CCC=C(C)C)CC(OC)=O.[O:24]=[C:25]([CH2:33][CH2:34][CH:35]=[C:36]([CH3:48])[CH2:37][CH2:38][CH:39]=[C:40]([CH3:47])[CH2:41][CH2:42][CH:43]=[C:44]([CH3:46])[CH3:45])[CH2:26][P:27](=[O:32])([O:30]C)[O:28]C>>[OH:24][CH:25]([CH2:33][CH2:34][CH:35]=[C:36]([CH3:48])[CH2:37][CH2:38][CH:39]=[C:40]([CH3:47])[CH2:41][CH2:42][CH:43]=[C:44]([CH3:46])[CH3:45])[CH2:26][P:27](=[O:28])([OH:32])[OH:30]

参加物

3

反応物 2

HCID 54245426Methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoateHCID 54462394Dimethyl [2-oxo-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonate

生成物 1

HCID 54248241[2-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trienyl]phosphonic acid

実験手順

This compound was prepared similarly by the method described in Step 2 of Example 1 except that methyl 3-oxo-7,11,15-trimethylhexadeca-6,10,14-trienoate was replaced by dimethyl [2-oxo-6,10, 14-trimethyl-pentadeca-5,9,13-trienyl]phosphonate and the product from this reaction was used in the hydrolysis step similarly to the method used in Step 2 in Example 2 to give, after lyophilization, title compound as a nearly colorless gum.

後処理

  1. customThis compound was prepared similarly by the method
  2. customthe product from this reaction was used in the hydrolysis step similarly to the method
  3. customto give

出典と根拠

ORDレコード
ord-fc0d33c74d1d4d298a588501bf5a2486
出典データセット
uspto-grants-1994_03
特許番号
US05298655

関連ノート

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