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4,4'-Dimethoxydiphenylamine → 4-Methyltriphenylamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4,4'-Dimethoxydiphenylamine | HCID 7571 | — |
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 反応物 | 4-Iodotoluene | HCID 12207 | — |
| 反応物 | sodium 2-methylpropan-2-olate | HCID 178418730 | — |
| 溶媒 | O-Xylene | HCID 7237 | — |
| 生成物 | 4-Methyltriphenylamine | HCID 11299928 | — |
反応手順
9.70 g (57.3 mmols) of N,N-diphenylamine (31a), 12.5 g (57.3 mmols) of 4-iodotoluene (32b), 6.61 g (68.8 mmols) of t-BuONa, 260 mg (1.15 mmols) of Pd(CH3COO)2 and 1.20 g (4.58 mmols) of triphenylphosphine were dissolved in xylene and refluxed in an atmosphere of nitrogen for 4 hours.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06979746B2 |
| 出典データセット | uspto-grants-2005_12 |
| ORD ID | ord-d74503ffc1d245c6b4aa61674ca5a104 |
| 出典メモ | uspto-grants-2005_12 |