Sodium Cyanide → 2-Phenylbut-3-enenitrile

反応式

[CH:1]([CH:3](Cl)[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[CH2:2].[C-:11]#[N:12].[Na+]>>[CH:1]([CH:3]([C:11]#[N:12])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[CH2:2]

参加物

反応物 2

HCID 8929Sodium Cyanide

HCID 11768772Benzene, 1-(chloromethyl)-3(or 4)-ethenyl-

生成物 1

HCID 147675092-Phenylbut-3-enenitrile

実験手順

a procedure according to A. Zerroukhi, A. Ainser, A. Arsac, N. Mignard, and B. Marculescu, Polymer Bulletin, 42, 535, 1999, is used. Initially, vinylbenzyl chloride is reacted with sodium cyanide to give vinylbenzyl cyanide, which is then reacted with ethanolamine to give the vinylbenzyloxazoline.

出典と根拠

ORDレコード: ord-fe2faf524b034320886bde9941a28ca2
出典データセット: uspto-grants-2009_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07528404B2

反応ノート

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