Phenylphosphonic Acid → Phosphonic acid, P-phenyl-, zinc salt (1:1)

HRID 492043

反応式

HRID 492043 の反応式
[C:1]1([P:7](=[O:10])([OH:9])[OH:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[O-2].[Zn+2:12]>O>[C:1]1([P:7](=[O:8])([O-:10])[O-:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Zn+2:12]

参加物

4

反応物 2

HCID 15295Phenylphosphonic AcidHCID 3007857Zinc Oxide

生成物 1

HCID 15878909Phosphonic acid, P-phenyl-, zinc salt (1:1)収率 98%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

In a glass ball mill container having a volume of 900 mL, 1000 g of 1 mmφ zirconia beads were charged, further 17.0 g (108 mmol) of phenylphosphonic acid (manufactured by Nissan Chemical industries, Ltd.), 8.78 g (108 mmol) of zinc oxide and 231 g of water were mixed, stirred at 170 rpm for 20 hours at room temperature. Then the slurry was separated from zirconia beads, and the separated slurry was filtered, and the wet cake was fully washed with water. Thereafter, the slurry was dried at 150° C. to obtain 23.4 g (yield 98%) of the aimed product as white crystal. The average particle diameter was 1.1 μm with a laser diffraction type particle size distribution meter (manufactured by Seishin Enterprise Co., Ltd., PRO-7000S).

後処理

  1. additionwere charged
  2. customThen the slurry was separated from zirconia beads
  3. filtrationthe separated slurry was filtered
  4. washthe wet cake was fully washed with water
  5. customThereafter, the slurry was dried at 150° C.

出典と根拠

ORDレコード
ord-505303cac5f6443b8fa3eac4a29002a2
出典データセット
uspto-grants-2009_05
特許番号
US07531585B2

関連ノート

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