化工社化工社 化学情報印刷レポート · 研究参考用
Tetrahydrothiophene → 1-(3,3-Dimethyl-2-oxobutyl)thiolan-1-ium bromide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Tetrahydrothiophene | HCID 1127 | — |
| 反応物 | Bromopinacolone | HCID 21642 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 1-(3,3-Dimethyl-2-oxobutyl)thiolan-1-ium bromide | HCID 22564578 | — |
反応手順
70.2 Parts of tetrahydrothiophene was dissolved in 750 parts of acetone, and 150 parts of 1-bromo-3,3-dimethyl-2-butanone was added dropwise thereto. After the mixture was stirred at room temperature for 24 hours, white solid obtained was filtered, washed with acetone and dried to obtain 161.3 parts of 1-(3,3-dimethyl-2-oxobutyl)tetrahydrothiophenium bromide in the form of white crystals.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07531686B2 |
| 出典データセット | uspto-grants-2009_05 |
| ORD ID | ord-4efe8ae645ce4c51b6e4a7eaecb65e22 |
| 出典メモ | uspto-grants-2009_05 |