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HRID 492266作成日:2026年10月27日

Tetrahydrothiophene → 1-(3,3-Dimethyl-2-oxobutyl)thiolan-1-ium bromide

https://huagongshe.com/reaction/492266

反応式

関与物質

役割名称HCID仕込み量
反応物TetrahydrothiopheneHCID 1127—
反応物BromopinacoloneHCID 21642—
溶媒AcetoneHCID 180—
生成物1-(3,3-Dimethyl-2-oxobutyl)thiolan-1-ium bromideHCID 22564578—

反応手順

70.2 Parts of tetrahydrothiophene was dissolved in 750 parts of acetone, and 150 parts of 1-bromo-3,3-dimethyl-2-butanone was added dropwise thereto. After the mixture was stirred at room temperature for 24 hours, white solid obtained was filtered, washed with acetone and dried to obtain 161.3 parts of 1-(3,3-dimethyl-2-oxobutyl)tetrahydrothiophenium bromide in the form of white crystals.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US07531686B2
出典データセットuspto-grants-2009_05
ORD IDord-4efe8ae645ce4c51b6e4a7eaecb65e22
出典メモuspto-grants-2009_05