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Triethylamine → N'-[(2'-nitro-1,1'-biphenyl-4-yl)methyl]-N'-pentyl-N-(2,4,6-trifluorophenyl)urea
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | P,P-Diphenylphosphinic azide | HCID 199401 | — |
| 反応物 | 2,4,6-Trifluorobenzoic acid | HCID 520373 | — |
| 反応物 | N-[(2'-nitro-1,1'-biphenyl-4-yl)methyl]-N-pentylamine | HCID 17860716 | — |
| 生成物 | N'-[(2'-nitro-1,1'-biphenyl-4-yl)methyl]-N'-pentyl-N-(2,4,6-trifluorophenyl)urea | HCID 68850802 | 95% |
反応手順
Using 2,4,6-trifluorobenzoic acid (0.43 g), diphenylphosphoryl azide (0.68 g), triethylamine (0.25 g) and N-[(2′-nitro-1,1′-biphenyl-4-yl)methyl]-N-pentylamine (0.40 g), N′-[(2′-nitro-1,1′-biphenyl-4-yl)methyl]-N′-pentyl-N-(2,4,6-trifluorophenyl)urea (0.60 g) was obtained by a similar procedure as in Example 4. Yield: 95%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07531576B2 |
| 出典データセット | uspto-grants-2009_05 |
| ORD ID | ord-ad60fc8c99314aac82cf2db2c0b61c60 |
| 出典メモ | uspto-grants-2009_05 |