関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Isoamyl Nitrite | HCID 8053 | — |
| 反応物 | Tetrafluoroboric acid | HCID 28118 | — |
| 反応物 | 4-Amino-3,5-dichlorobenzonitrile | HCID 522706 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 2,6-Dichloro-4-cyanobenzenediazonium tetrafluoroborate | HCID 86609655 | 62.5% |
反応手順
To a solution of 4-amino-3,5-dichlorobenzonitrile (2.00 g, 10.63 mmol) in acetonitrile (12 ml) was added dropwise tetrafluoroboric acid (2.80 ml, 21.27 mmol). After stirring for 10 min, isoamyl nitrite (1.50 ml, 10.63 mmol) was added and the reaction mixture was cooled to 0° C. After a further 10 min, diethyl ether (50 ml) was added and the resulting precipitate was collected by filtration and dried to give the titled compound (1.9 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07538134B2 |
|---|
| 出典データセット | uspto-grants-2009_05 |
|---|
| ORD ID | ord-642f2c82542c4638be26f180b45fce07 |
|---|
| 出典メモ | uspto-grants-2009_05 |
|---|
