関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Bicyclo(2.2.1)heptane-2-methanol | HCID 21308 | — |
| 反応物 | HCID 178418287 | HCID 178418287 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Bicyclo[2.2.1]heptane-2-carbaldehyde | HCID 86864 | 42% |
反応手順
A stirred suspension of 2-norbornylmethanol (0.5 ml; 5.8 mmol) and PCC on Al2O3* in CH2Cl2 (25 ml) was stirred at 2-3° C. for 1 h and allowed to slowly warm up to rt. The reaction mixture was filtered and the solid material washed with CH2Cl2 (2×25 ml). The combined organic fractions were adsorbed onto silica and chromatographed to give 300 mg (42%) product as an oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06943159B1 |
|---|
| 出典データセット | uspto-grants-2005_09 |
|---|
| ORD ID | ord-99da1fecffe54b5291694c2e35173483 |
|---|
| 出典メモ | uspto-grants-2005_09 |
|---|
