Hydrogen iodide → Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodo-

HRID 496959

反応式

HRID 496959 の反応式
[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:23]([CH:26]=[CH2:27])([F:25])[F:24])([F:22])[F:21])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2].[Al](I)(I)[I:29].I>>[C:1]([C:5]([C:8]([C:11]([C:14]([C:17]([C:20]([C:23]([CH2:26][CH2:27][I:29])([F:24])[F:25])([F:21])[F:22])([F:18])[F:19])([F:16])[F:15])([F:13])[F:12])([F:10])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2]

参加物

4

反応物 3

HCID 24841Hydrogen iodideHCID 82222Aluminum iodideHCID 889901H,1H,2H-Perfluoro-1-decene

生成物 1

HCID 74885Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodo-

実験手順

The same process as in Example 1 was conducted except that 41 g of CF3(CF2)7CH═CH2, 12 g of CaSO4/C (25/75 mass %) instead of AlI3, and 24 g of hydrogen iodide gas were used. CF3(CF2)7CH2CH2I was produced at a conversion rate of 90% and at a selectivity of 100%.

出典と根拠

ORDレコード
ord-f4d0ff03268a4e70bfd9e0623b6f5d6e
出典データセット
uspto-grants-2005_09
特許番号
US06946582B2

関連ノート

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