反応式
COC(=O)C([C:10]([C:12]1[C:29]2=[C:30]3[C:19](C4C5C(=[CH:25][CH:26]=[CH:27][C:28]2=5)C=CC=4)=[CH:18][CH:17]=[CH:16][C:15]3=[CH:14][CH:13]=1)=[O:11])CCCCC.[CH3:33][O:34][C:35](=[O:60])[CH:36]([C:38]([C:40]1C2=C3C(C4C5C(=CC=CC2=5)C=CC=4)=CC=C[C:43]3=[CH:42][CH:41]=1)=O)C.[Cl-].COC(=O)CCC[CH2:68][CH2:69][CH2:70][CH2:71][CH2:72][C:73](O)=O.C1C2=C3C(C4C5C(=CC=CC2=5)C=CC=4)=CC=CC3=CC=1>>[CH3:33][O:34][C:35](=[O:60])[CH2:36][CH2:38][CH2:40][CH2:41][CH2:42][CH2:43][C:10]([C:12]1[CH:13]=[CH:14][C:15]2[C:16]3[CH:17]=[CH:18][CH:19]=[C:68]4[C:69]=3[C:70]([C:25]3[C:30]=2[C:29]=1[CH:28]=[CH:27][CH:26]=3)=[CH:71][CH:72]=[CH:73]4)=[O:11]参加物
5
実験手順
The synthesis and purification of perylenoylheptanoic acid methyl ester was achieved as described for perylenoyl propanoic acid methyl ester starting from sebacic acid monomethyl ester chloride and perylene. Yield 73.7%. Rf 0.23 (system 1). 1H-NMR (CDCl3) (δ, ppm): 1.43 (m, 4H, 4-CH2, 5-CH2), 1.67 (m, 2H, 3-CH2), 1.82 (m, 2H, 6-CH2), 2.32 (t, 2H, Ja,b=J2,3 7.42 Hz, 2-CH2), 3.05 (t, 2H, Ja,b=J6,7 7.35 Hz, 7-CH2), 3.69 (s, 3H, CH3), 7.43-7.64 (m, 3H, Ar), 7.74 (t, 2H, J 8.26 Hz, Ar), 7.84 (d, 1H, J 7.92 Hz, Ar), 8.13-8.30 (m, 4H, Ar), 8.48 (d, 1H, J 7.54 Hz, Ar).
出典と根拠
- ORDレコード
- ord-1f5d0b644e494508a166f1b9941fe5da
- 出典データセット
- uspto-grants-2010_08
- 特許番号
- US07772402B2
関連ノート
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