Ammonia → 4-Amino-3,5-dichlorobenzotrifluoride

HRID 504088

反応式

HRID 504088 の反応式
[Cl:1][C:2]1[CH:3]=[C:4]([C:10]([F:13])([F:12])[F:11])[CH:5]=[C:6]([Cl:9])[C:7]=1Cl.[NH3:14]>O>[Cl:1][C:2]1[CH:3]=[C:4]([C:10]([F:13])([F:12])[F:11])[CH:5]=[C:6]([Cl:9])[C:7]=1[NH2:14]

参加物

4

反応物 2

HCID 222Ammonia2 回HCID 27333991,2,3-Trichloro-5-(trifluoromethyl)benzene

生成物 1

HCID 1410944-Amino-3,5-dichlorobenzotrifluoride

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Into a 1000 ml high-pressure reaction vessel add 200 g 3,4,5-Trichlorobenzotrifluoride and 145 g water, enclose the reaction vessel, fill liquid ammonia 380 g, close the valve, start agitation, slowly increase temperature to 160° C. and pressure to 10.0 MPa, make timed temperature-retention under controlled temperature 165° C. and controlled pressure 11.5 MPa for 8 h, then release the pressure and discharge ammonia.

後処理

  1. customInto a 1000 ml high-pressure reaction vessel
  2. customclose the valve
  3. customto 160° C.
  4. customunder controlled temperature 165° C. and controlled pressure 11.5 MPa
  5. customfor 8 h

出典と根拠

ORDレコード
ord-52f2556c81fd4dacbea8a61b3f3d9cef
出典データセット
uspto-grants-2010_08
特許番号
US07777079B2

関連ノート

読み込み中…