Methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate → Methyl 10-methylacridan-9-carboxylate
反応式
FC(F)(F)S([O-])(=O)=O.[CH3:9][N+:10]1[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[C:17]([C:24]([O:26][CH3:27])=[O:25])=[C:16]2[C:11]=1[CH:12]=[CH:13][CH:14]=[CH:15]2>CO>[CH3:9][N:10]1[C:23]2[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=2)[CH:17]([C:24]([O:26][CH3:27])=[O:25])[C:16]2[CH:15]=[CH:14][CH:13]=[CH:12][C:11]1=2参加物
3
実験手順
A solution of methyl 10-methylacridinium-9-carboxylate trifluoromethanesulfonate (75), 4.25 parts, in methanol is reduced as described in Example I to give 3.2 parts of methyl 10-methylacridan-9-carboxylate and the isolated product has the following structure confirmed by NMR.
出典と根拠
- ORDレコード
- ord-2aa4353cb062406ca28cacf1d0632f6c
- 出典データセット
- uspto-grants-2010_08
- 特許番号
- US07781229B2
反応ノート
読み込み中…