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HRID 51010作成日:2026年10月26日

Acetic acid, (1,3-dihydro-2H-inden-2-ylidene)-, ethyl ester → Ethyl 2-(2,3-dihydro-1H-inden-2-yl)acetate

https://huagongshe.com/reaction/51010

反応式

関与物質

役割名称HCID仕込み量
反応物Acetic acid, (1,3-dihydro-2H-inden-2-ylidene)-, ethyl esterHCID 10631946—
触媒PalladiumHCID 23938—
溶媒Ethyl AcetateHCID 8857—
生成物Ethyl 2-(2,3-dihydro-1H-inden-2-yl)acetateHCID 1010435994%

反応手順

To a solution of ethyl 1,3-dihydro-2H-inden-2-ylideneacetate (302 mg, 1.49 mmol) in EtOAc (10 mL) was added 5% Pd/C (76 mg) and H2 was bubbled through the slurry for 20 h. The slurry was then filtered through Celite and the organic solution was concentrated in vacuo. Ethyl 2,3-dihydo-1H-inden-2-ylacetate (285 mg, 94%) was isolated as a colorless oil without purification.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US06713471B1
出典データセットuspto-grants-2004_03
ORD IDord-a54f5142b7224ac08d0149ff911a7335
出典メモuspto-grants-2004_03