関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Methanesulfonic Acid | HCID 6395 | — |
| 反応物 | Acrylic Acid | HCID 6581 | — |
| 反応物 | 1-Octene | HCID 8125 | — |
| 反応物 | 4-Methoxyphenol | HCID 9015 | — |
| 触媒 | Cupric chloride dihydrate | HCID 61482 | — |
| 生成物 | Octyl acrylate | HCID 17258 | — |
反応手順
A mixture of 15.0 g (134 mmoles, 3 eq) of 1-octene, 3.21 g (44.6 mmoles, 1 eq) of acrylic acid, 0.257 g (2.67 mmoles, 0.06 eq) of methanesulfonic acid, 0.0277 g of MEHQ and 0.0034 g of copper(II) chloride dihydrate was heated at 105° C. for 22 hours to give 2.5% conversion to octyl acrylate based on acrylic acid consumed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09102774B2 |
|---|
| 出典データセット | uspto-grants-2015_08 |
|---|
| ORD ID | ord-5a70f24bd13042c58ae2ec49962b0a4a |
|---|
| 出典メモ | uspto-grants-2015_08 |
|---|
